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KMID : 0903519940370010025
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Journal of the Korean Society of Agricultural Chemistry and Biotechnology
1994 Volume.37 No. 1 p.25 ~ p.29
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The diastereoselective synthesis of 2 - methyl - 5(S) - hexanolide
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Abstract
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2-methyl-5(S)-hexanolide(1); the major component of pheromonal blend of the male carpenter bee was synthesized via Homer-Emmons reaction from Ethyl(S)-3-hydroxybutyrate(2a) which had been obtained by Baker´s Yeast reduction in overall yield 39%.
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